-
paired up. Free
stannylenes are
stabilized by
steric protection.
Adducts with
Lewis bases are also known. The
first persistent stannylene, [(Me3Si)2CH]2Sn...
-
attributed to the "inert pair effect". Organotin(II)
compounds include both
stannylenes (formula: R2Sn, as seen for
singlet carbenes) and
distannylenes (R4Sn2)...
-
Examples include (pentamethylcyclopentadienyl)aluminium(I) (Al(I)),
stannylenes (Sn(II)), and
diphosphenes (P(I)). Thus
organic derivatives of the electropositive...
- the
synthesis of
carbohydrates and
other polyhydroxylated compounds.
Stannylene acetals have been used to
efficiently achieve this transformation. The...
-
regiospecific benzylation and
allylation of polyhydroxy-compounds via
their stannylene derivatives in non-polar solvents", in: J. Chem. Soc.,
Perkin Trans. 1...
- doi:10.1021/np030742g. Neumann,
Wilhelm P. (1991). "Germylenes and
stannylenes".
Chemical Reviews. 91 (3): 311–334. doi:10.1021/cr00003a002. ISSN 0009-2665...
-
decreasing dimerization energy down
Group 14,
while monohalogenated stannylenes and
plumbylenes dimerize via the halogen-bridging mode, monohalogenated...
- "Synthesis and
Structure of
Stable Tri-tert-butylgermyl-Substituted
Stannylene and Germylene". Organometallics. 20 (22): 4460–4462. doi:10.1021/om010591h...
- are silylenes, R2Si:,
germylenes R2Ge: (example diphosphagermylene),
stannylenes R2Sn: and
plumbylenes R2Pb:,
collectively known as
metallylenes and regarded...
