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Stannylenes (R2Sn:) are a
class of organotin(II)
compounds that are
analogues of carbene.
Unlike carbene,
which usually has a
triplet ground state, stannylenes...
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attributed to the "inert pair effect". Organotin(II)
compounds include both
stannylenes (formula: R2Sn, as seen for
singlet carbenes) and
distannylenes (R4Sn2)...
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Examples include (pentamethylcyclopentadienyl)aluminium(I) (Al(I)),
stannylenes (Sn(II)), and
diphosphenes (P(I)). Thus
organic derivatives of the electropositive...
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regiospecific benzylation and
allylation of polyhydroxy-compounds via
their stannylene derivatives in non-polar solvents", in: J. Chem. Soc.,
Perkin Trans. 1...
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decreasing dimerization energy down
Group 14,
while monohalogenated stannylenes and
plumbylenes dimerize via the halogen-bridging mode, monohalogenated...
- the
synthesis of
carbohydrates and
other polyhydroxylated compounds.
Stannylene acetals have been used to
efficiently achieve this transformation. The...
- "Synthesis and
Structure of
Stable Tri-tert-butylgermyl-Substituted
Stannylene and Germylene". Organometallics. 20 (22): 4460–4462. doi:10.1021/om010591h...
- are silylenes, R2Si:,
germylenes R2Ge: (example diphosphagermylene),
stannylenes R2Sn: and
plumbylenes R2Pb:,
collectively known as
metallylenes and regarded...
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catecholborane to
regenerate the
germylene compound.
Carbene analogs Silylene Stannylene Mizuhata, Yoshiyuki; Sasamori, Takahiro; Tokitoh,
Norihiro (2009). "Stable...
