- the
molecules of [
SnCl4(H2O)2]
through hydrogen bonds. A
pentahydrate has also been crystallized. In cis-
SnCl4(H2O)2·3H2O, the
Sn-Cl
bonds are 238.3...
-
SnH4. It is a
colourless gas and the tin
analogue of methane.
Stannane can be
prepared by the
reaction of
SnCl4 and Li[AlH4].
SnCl4 + Li[AlH4] →
SnH4...
-
chloride (
SnCl4).
SnCl2 has a lone pair of electrons, such that the
molecule in the gas
phase is bent. In the
solid state,
crystalline SnCl2
forms chains...
- tin
metal to give
SnCl4 whereas the
reaction of
hydrochloric acid and tin
produces SnCl 2 and
hydrogen gas.
Alternatively SnCl4 and
Sn combine to stannous...
- MgO +CO2 4 SnO2 + 6 FeCl2 → 2
SnCl2 + 2
SnCl4 + 2 Fe3O4
SnO2
converts to the
monoxide at 1500 °C: 2
SnO2 → 2
SnO + O2
SnO2 is
insoluble in water. It dissolves...
- near
reflux (114 °C):
SnCl4 + 2 H2SO4 →
Sn(SO4)2 + 4 HCl
Pyrolysis of
anhydrous tin(IV)
sulfate at 150 °C - 200 °C:
Sn(SO4)2 →
SnO2 + 2 SO3 To further...
- in the case of
organotin compounds): 3 R4Sn +
SnCl4 → 4 R3SnCl R4Sn +
SnCl4 → 2 R2SnCl2 R4Sn + 3
SnCl4 → 4 RSnCl3 A
related method involves redistribution...
- Ti
Cl4 contains a
variety of
other volatile halides,
including vanadyl chloride (VOCl3),
silicon tetrachloride (Si
Cl4), and tin
tetrachloride (
SnCl4),...
- another. The
melting point of
SnF4 is much
higher (700 °C) than the
other tin(IV) halides: (
SnCl4, −33.3 °C;
SnBr4, 31 °C;
SnI4, 144 °C). The
structure can...
- chloride,
containing tin in its
highest oxidation state: 4 HCl + 2 HNO3 +
Sn →
SnCl4 + NO2 + NO + 3 H2O It can
react with iron
pyrite to form Iron(III) chloride:...
