Definition of Silylium. Meaning of Silylium. Synonyms of Silylium

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Definition of Silylium

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Meaning of Silylium from wikipedia

- A silylium ion is a reactive silyl-containing cation with the formula SiR+ 3. With three rather than the usual four bonds to Si, silylium ions are the...
- displacement mechanism. A silylium ion is a silicon cation with only three bonds and a positive charge. The abstraction of the silylium ion is seen from the...
- Lin, L.; Lambert, J. B. (2002). "Crystallographic Evidence for a Free Silylium Ion". Science. 297 (5582): 825–827. Bibcode:2002Sci...297..825K. doi:10...
- earth metal complexes, p-block main group compounds (e.g. AlCl3, AN 87; silylium cations; [E(bipy)2]3+ (E = P, As, Sb, Bi) cations; cationic 4 coordinate...
- diffusion control. Carbene analogs N-heterocyclic silylene Silenes, R2Si=SiR2 Silylium ions, protonated silylenes IUPAC Chemical Nomenclature and Structure Representation...
- C6H+7 (protonated benzene) tropylium, C7H+7 (protonated tropylidene) silylium cations, R3Si+ (protonated silylenes) nitrenium cations, R2N+ (protonated...
- Heterolytic cleavage of the Si-H bond from PhMe2SiH by the FLP catalyst forms a silylium and hydridoborate ionic complex. Metal free hydrogenation of unactivated...
- surprising system Ga+/HSiR3/olefin, proof of oxidation with subvalent Ga+ and silylium catalysis with perfluoroalkoxyaluminate anions". Chemical Science. 13 (2):...
- hydride ∞ 1[(SiH)−] can be formed. General organic compounds are termed silylium ions. Klinkhammer, Karl W. (September 1997). "Tris(trimethylsilyl)silanides...
- and Other Hydrodehalogenation of Aliphatic Carbon−Halogen Bonds Using Silylium Catalysis Christos Douvris, C. M. Nagaraja, Chun-Hsing Chen, Bruce M. Foxman...