-
Silylene is a
chemical compound with the
formula SiR2. It is the
silicon analog of carbene.
Silylene rapidly when condensed.
Silylenes are
formal derivatives...
- emplo**** in the trapping:
Another classic but
elusive family of
targets are
silylenes,
analogues of carbenes. It was
proposed that
dechlorination of dimethyldichlorosilane...
- carbenes, N-heterocyclic
silylenes are
known to act as
ligands in a
range of
metal complexes.
Unlike most non-NHSi
silylenes which are
Lewis acidic, stable...
-
organogermanium compounds,
organotin compounds,
organolead compounds Silylenes, the
carbene counterparts Silylenoids, the
carbenoid counterparts Decamethylsilicocene...
- 2-dihalodisilane, by retro-Diels–Alder fragmentation, by
dimerization of
silylenes, by
photofragmentation of cyclopolysilanes, or by
rearrangement of silylsilylenes...
- ω-(trimethylsilyloxy)poly[oxy(dimethyl)
silylene]- co-[oxy(methyl)(2-{4-[2,2-bis(ethoxycarbonyl)vinyl]phenoxy}- 1-methyleneethyl)
silylene]- co-[oxy(methyl)(2-(4-[2...
- are the
silicon pendants of
carbenoid and both
compounds have
carbene or
silylene like properties.
Silylenoids are
encountered as
reactive intermediates...
-
silicon analogues of
carbenium ions. They can be
viewed as
protonated silylenes.
Early efforts to
generate these cations produced salts of the pyridine...
- tropylium, C7H+7 (protonated tropylidene)
silylium cations, R3Si+ (protonated
silylenes)
nitrenium cations, R2N+ (protonated nitrenes)
phosphinidenium cations...
- Haaf, Michael; Schmedake,
Thomas A.; West,
Robert (2000-10-01). "Stable
Silylenes".
Accounts of
Chemical Research. 33 (10): 704–714. doi:10.1021/ar950192g...
