-
Silylene is a
chemical compound with the
formula SiR2. It is the
silicon analog of carbene. Due to
presence of a
vacant p orbital,
silylene rapidly reacts...
- An N-Heterocyclic
silylene (NHSi) is a
neutral heterocyclic chemical compound consisting of a
divalent silicon atom
bonded to two
nitrogen atoms. The isolation...
- are the
silicon pendants of
carbenoid and both
compounds have
carbene or
silylene like properties.
Silylenoids are
encountered as
reactive intermediates...
- ω-(trimethylsilyloxy)poly[oxy(dimethyl)
silylene]- co-[oxy(methyl)(2-{4-[2,2-bis(ethoxycarbonyl)vinyl]phenoxy}- 1-methyleneethyl)
silylene]- co-[oxy(methyl)(2-(4-[2...
- emplo**** in the trapping:
Another classic but
elusive family of
targets are
silylenes,
analogues of carbenes. It was
proposed that
dechlorination of dimethyldichlorosilane...
- This
distortion is
rationalized by the
stability of the
corresponding silylene fragments,
although disilenes do not
typically dissociate. The distorted...
- 48
hours and with heat
induces cage
opening in the same
manner as the
silylene reaction to
generate H2C=P(tBuC)3.
Reaction of this
product with tBu3C3P...
-
decamethylsilicocene through salt
metathesis from an N-heterocyclic carbene-stabilized
silylene. This
synthetic route avoids the
synthesis of the bis(pentamethylcyclo...
-
organogermanium compounds,
organotin compounds,
organolead compounds Silylenes, the
carbene counterparts Silylenoids, the
carbenoid counterparts Decamethylsilicocene...
-
Phosphasilenes with 4-coordinate silicon,
which can also be
viewed as
silylene-stabilized phosphinidene, can be
synthesized based on the reactivities...
