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Silylation is the
introduction of one or more (usually)
substituted silyl groups (R3Si) to a molecule.
Silylations are core
methods for
production of organosilicon...
-
trifluoromethanesulfonic acid. It is
commonly used as a
Lewis acid catalyst, e.g. in
silylations. A
white powder, zinc
triflate is
commercially available,
though some...
- Volumes, vol. 8, p. 616. Kuwajima, I.; Nakamura, E.; Hashimoto, K. (1990). "
Silylation of
Ketones with
Ethyl Trimethylsilacetate: (Z)-3-Trimethylsiloxy-2-Pentene"...
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laboratory gl****ware,
making the
surfaces more lipophilic. By the
process of
silylation,
polar functional groups such as
alcohols and
amines readily undergo reaction...
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adulteration by
added sugars with
these methods.
Derivatization using silylation reagents is
commonly used. Also, the
proportions of di- and trisaccharides...
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Kerry N. Betz,
Alexey Fedorov,
Brian Stoltz,
Robert H.
Grubbs (2015). "
Silylation of C–H
bonds in
aromatic heterocycles by an Earth-abundant
metal catalyst"...
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organosilicon compounds is
found to be very
efficient and
replaced TMSCl reagent.
Silylation of
glutamic acid with
excess hexamethyldisilazane and
catalytic TMSCl...
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which all have an
abundance of
hydroxyl groups.
Silanization differs from
silylation,
which usually refers to
attachment of
organosilicon groups to molecular...
- Wilson, Jake W.; Hartwig, John F. (2023). "Transition-Metal-Catalyzed
Silylation and
Borylation of C–H
Bonds for the
Synthesis and
Functionalization of...
- chloride.
Related to its
tendency to hydrolyze,
TMSOTf is
effective for
silylation of alcohols: (CH3)3SiO3SCF3 + ROH + Et3N → ROSi(CH3)3Si + [Et3NH]O3SCF3...
