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Silylation is the
introduction of one or more (usually)
substituted silyl groups (R3Si) to a molecule.
Silylations are core
methods for
production of organosilicon...
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trifluoromethanesulfonic acid. It is
commonly used as a
Lewis acid catalyst, e.g. in
silylations. A
white powder, zinc
triflate is
commercially available,
though some...
- Volumes, vol. 8, p. 616. Kuwajima, I.; Nakamura, E.; Hashimoto, K. (1990). "
Silylation of
Ketones with
Ethyl Trimethylsilacetate: (Z)-3-Trimethylsiloxy-2-Pentene"...
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laboratory gl****ware,
making the
surfaces more lipophilic. By the
process of
silylation,
polar functional groups such as
alcohols and
amines readily undergo reaction...
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adulteration by
added sugars with
these methods.
Derivatization using silylation reagents is
commonly used. Also, the
proportions of di- and trisaccharides...
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organosilicon compounds is
found to be very
efficient and
replaced TMSCl reagent.
Silylation of
glutamic acid with
excess hexamethyldisilazane and
catalytic TMSCl...
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Kerry N. Betz,
Alexey Fedorov,
Brian Stoltz,
Robert H.
Grubbs (2015). "
Silylation of C–H
bonds in
aromatic heterocycles by an Earth-abundant
metal catalyst"...
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react more rapidly).
Silylation is most
commonly accomplished using HMDS,
which evolves ammonia as the only
byproduct of
silylation.
Catalytic or stoichiometric...
- Wilson, Jake W.; Hartwig, John F. (2023). "Transition-Metal-Catalyzed
Silylation and
Borylation of C–H
Bonds for the
Synthesis and
Functionalization of...
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Enolates can be
trapped by the
addition of
electrophiles at oxygen.
Silylation gives silyl enol ether.
Acylation gives esters such as
vinyl acetate....
