- sugar. The silyl-Hilbert-Johnson (or Vorbrüggen) reaction,
which employs silylated heterocyclic bases and
electrophilic sugar derivatives in the presence...
- (Me = CH3): ROH + CF3C(OSiMe3)NSiMe3 → CF3C(O)NH(SiMe3) + ROSiMe3
These silylated derivatives are
amenable to
analysis or
further mani****tion. Siloxanes...
-
substitution reactions with acid chlorides. The
terminal nitrogen can also be
silylated.
Transition metal dinitrogen complex Nitrogen fixation Hidai, Masanobu...
- solids. Alcohols,
carboxylic acids, amines, thiols, and
phosphates can be
silylated. This is done
through an SN2
reaction as the
formerly mentioned functional...
- chromatography-m**** spectrometry, HMDS is
added to the
analyte to
create silylated diagnostic products during pyrolysis, in
order to
enhance detectability...
-
hydrolyze much more
slowly than the
trimethylsilyl ethers. It also can
silylate terminal alkynes. The
triflate derivative (Me3C)Me2SiOTf is used similarly...
- as a mild base. As a
deprotecting agent, TBAF in DMSO will
convert O-
silylated enolates into carbonyls. With C-Si bonds, TBAF
gives carbanions that can...
- the
conversion of
tungsten hexachloride to the
tetrachloride using the
silylated pyrazine reagent: Me3SiNC4Me4NSiMe3 + WCl6 + 2 thf → NC4Me4N + 2 Me3SiCl...
-
phosphoranes 1 or
linear alkyl transfer products 2. More
practical is the use of
silylated phosphorus sources,
which undergo intramolecular silyl group transfer...
-
organosilicon compounds synthesized using the Wurtz–****ig
reaction include silylated calixarenes and vinylsilanes.
Wurtz reaction Wang,
Zerong (2010). "Wurtz–****ig...
