Definition of Silylated. Meaning of Silylated. Synonyms of Silylated

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Definition of Silylated

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Meaning of Silylated from wikipedia

- sugar. The silyl-Hilbert-Johnson (or Vorbrüggen) reaction, which employs silylated heterocyclic bases and electrophilic sugar derivatives in the presence...
- follows: ROH + NEt3 → RO− + H−NEt+3 RO− + Cl−SiMe3 → RO−SiMe3 + Cl− Other silylating agents include bis(trimethylsilyl)acetamide (BSA). The reaction of BSA...
- (Me = CH3): ROH + CF3C(OSiMe3)NSiMe3 → CF3C(O)NH(SiMe3) + ROSiMe3 These silylated derivatives are amenable to analysis or further mani****tion. Siloxanes...
- chromatography-m**** spectrometry, HMDS is added to the analyte to create silylated diagnostic products during pyrolysis, in order to enhance detectability...
- Synthesis of aromatic nitriles via silylated cyanohydrins...
- organosilicon compounds synthesized using the Wurtz–****ig reaction include silylated calixarenes and vinylsilanes. Wurtz reaction Wang, Zerong (2010). "Wurtz–****ig...
- hydrolyze much more slowly than the trimethylsilyl ethers. It also can silylate terminal alkynes. The triflate derivative (Me3C)Me2SiOTf is used similarly...
- as a mild base. As a deprotecting agent, TBAF in DMSO will convert O-silylated enolates into carbonyls. With C-Si bonds, TBAF gives carbanions that can...
- phosphaalkynes via the elimination of hexamethyldisiloxane (HMDSO) from certain silylated phosphaalkenes with the general structure RO−(Me3Si)C=P−SiMe3. These phosphaalkenes...
- carbon-carbon bond: RCH=O + (CH3)3SiC≡N → N≡C–CHR–OSi(CH3)3 The product is an O-silylated cyanohydrin. One use of this reagent is to convert pyridine-N-oxides into...