-
hydrolyze much more
slowly than the
trimethylsilyl ethers. It also can
silylate terminal alkynes. The
triflate derivative (Me3C)Me2SiOTf is used similarly...
- the
silylation of
alcohols in
excellent yields. 3) HMDS can be used to
silylate laboratory gl****ware and make it hydrophobic, or
automobile gl****, just...
-
commercial scales.
Silyl ether Hydrosilylation Pape,
Peter G. (2017). "
Silylating Agents". Kirk-Othmer
Encyclopedia of
Chemical Technology. pp. 1–15. doi:10...
-
catalyzing additional reactants: One approach,
demonstrated by Evans, is to
silylate the
aldol adduct. A
silicon reagent such as
TMSCl is
added in the reaction...
- (Me = CH3): ROH + CF3C(OSiMe3)NSiMe3 → CF3C(O)NH(SiMe3) + ROSiMe3
These silylated derivatives are
amenable to
analysis or
further mani****tion. Siloxanes...
- sugar. The silyl-Hilbert-Johnson (or Vorbrüggen) reaction,
which employs silylated heterocyclic bases and
electrophilic sugar derivatives in the presence...
- as a mild base. As a
deprotecting agent, TBAF in DMSO will
convert O-
silylated enolates into carbonyls. With C-Si bonds, TBAF
gives carbanions that can...
-
Synthesis of
aromatic nitriles via
silylated cyanohydrins...
-
organosilicon compounds synthesized using the Wurtz–****ig
reaction include silylated calixarenes and vinylsilanes.
Wurtz reaction Wang,
Zerong (2010). "Wurtz–****ig...
- ISSN 0269-3879. PMID 35962484. S2CID 251540223. Pape,
Peter G. (2017). "
Silylating Agents". Kirk-Othmer
Encyclopedia of
Chemical Technology. pp. 1–15. doi:10...
