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Silylation is the
introduction of one or more (usually)
substituted silyl groups (R3Si) to a molecule.
Silylations are core
methods for
production of...
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Silyl-modified
polymers (SMP; also silane-modified polymers, modified-silane polymers, MS polymers, silane-terminated polymers, etc.) are
polymers terminating...
- In
organosilicon chemistry,
silyl enol
ethers are a
class of
organic compounds that
share the
common functional group R3Si−O−CR=CR2,
composed of an enolate...
- "super"
silyl groups of
which there exist two varieties: A
silicon group connected to
three trimethylsilyl groups makes a tri(trimethylsilyl)
silyl group...
-
prepared by
hydrolysis of
silyl chlorides: R 3SiCl + H2O → R 3SiOH + HCl Less
frequently silanols are
prepared by
oxidation of
silyl hydrides, a
reaction that...
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Silyl ethers are a
group of
chemical compounds which contain a
silicon atom
covalently bonded to an
alkoxy group. The
general structure is R1R2R3Si−O−R4...
- alkali. The
alkoxysilanes (
silyl ethers) of the type R3Si(OR') are slow to hydrolyze.
Compared to the
silyl ethers,
silyl acetates are
faster to hydrolyze...
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chemistry the
Brook rearrangement refers to any [1,n]
carbon to
oxygen silyl migration. The
rearrangement was
first observed in the late 1950s by Canadian...
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Rubottom oxidation is a useful, high-yielding
chemical reaction between silyl enol
ethers and
peroxyacids to give the
corresponding α-hydroxy carbonyl...
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alkyl and
vinyl silanes;
aldehydes and
ketones give
silyl ethers,
while esters provide alkyl silyl mixed acetals.
Hydrosilylation has been
called the "most...
