-
functional group R3SiO− (where the
three Rs may be different) is
called siloxy.
Siloxanes are
manmade and have many
commercial and
industrial applications...
-
compound bis(triethoxysilylpropyl)tetrasulfide is a cross-linking agent: the
siloxy groups link to
silica and the
polysulfide groups vulcanize with polyolefins...
- (CH3)3SiOH + HN3 The
compound adds to
ketones and
aldehydes to give the
siloxy azides and
subsequently tetrazoles: (CH3)3SiN3 + R2CO → R2C(N3)OSi(CH3)3...
- transfer. The use of
siloxy-containing
phosphorus sources has
greatly expanded the
scope of this reaction, as the
resulting α-
siloxy compounds can be converted...
- Prilezhaev-type
oxidation of the
silyl enol
ether with the
peroxyacid to form the
siloxy oxirane intermediate, acid-catalyzed ring-opening
yields an oxocarbenium...
- in the
synthesis periplanone B: The
corresponding neutral oxy-Cope and
siloxy-Cope
rearrangements failed,
giving only
elimination products at 200 °C....
- third-generation polymer. Its
patent claims that the
material uses two
siloxy macromers of
diverse sizes that, when used in combination,
produce very...
- (DX),
cyclosiloxanes di-Me, dimethylcyclopolysiloxane,
polydimethyl siloxy cyclics, polydimethylcyclosiloxane,
cyclomethicone and
mixed cyclosiloxane...
- Rawal, V. H. (1997). "Preparation and Diels−Alder
Reactivity of 1-Amino-3-
siloxy-1,3-butadienes".
Journal of
Organic Chemistry. 62 (16): 5252–5253. doi:10...
-
subsequent 1,3-Brook
rearrangement and
elimination cascade to
afford a
siloxy-methylene
enone and
release the catalyst. The Rauhut-Currier
reaction is...
