-
adopt with low
coordination numbers.
Examples include Ti(
silox)3, Nb(
silox)3(PMe3), and [Cr(
silox)3]−. The
sodium derivative,
which has salt-like properties...
- Tris(
silox)tantalum, Ta(SiOtBu3)3, is an
organotantalum complex bound with
three siloxide (this
siloxide has
three tert-butyl
groups attached to silicon...
- Bond
Cleavage of (
silox)3NbPMe3 (
silox = tBu3SiO)
under Dihydrogen Leads to (
silox)3Nb=CH2, (
silox)3Nb=PH or (
silox)3NbP(H)Nb(
silox)3, and CH4." Hirsekorn...
- for Clank. They then head to
Weeblesnog City, the
capital city of
planet Silox,
where the
Progs are
experimenting with a
device resembling the Dimensionator...
-
Strong Tantalum-to-Boron
Dative Interactions in (
silox)3Ta(BH3) and (
silox)3Ta(η2-B,Cl-BCl2Ph) (
silox = tBu3SiO)1".
Inorganic Chemistry. 46 (4): 1222–1232...
-
metathesis reactions. A very
bulky siloxide is tert-butyl3SiO−,
sometimes called silox.
Siloxides are
weaker net
donors than
alkoxides because pπ-d
donation has...
-
Trimethylsiloxide is a
lipophilic pseudohalide. It is a
source of
oxide dianion.
Sodium silox, NaOSi(tBu)3 (tBu = C(CH3)3) Pot****ium
trimethylsilanolate Sommer, L...
-
clusters include selenium tetrachloride,
tellurium tetrachloride, and
sodium silox.
Cubane clusters are
common throughout bioinorganic chemistry. Ferredoxins...
