- In
organic chemistry, a
sigmatropic reaction (from Gr**** τρόπος (trópos) 'turn') is a
pericyclic reaction wherein the net
result is one
sigma bond (σ-bond)...
- ylide. Many
ylides react in
sigmatropic reactions. The Sommelet-Hauser
rearrangement is an
example of a [2,3]-
sigmatropic reaction. The
Stevens rearrangement...
-
selection rules for an [i,j]-
sigmatropic rearrangement are as follows: For supra/supra or antara/antara [i,j]-
sigmatropic shifts, if i + j = 4n + 2 they...
- 2,3-
Sigmatropic rearrangements are a type of
sigmatropic rearrangements and can be
classified into two types.
Rearrangements of
allylic sulfoxides, amine...
-
rearrangement is an
extensively studied organic reaction involving the [3,3]-
sigmatropic rearrangement of 1,5-dienes. It was
developed by
Arthur C. Cope and Elizabeth...
-
release of
electronica band
Sigmatropic Sixteen Haiku &
Other Stories. A
subsequent limited edition 12-inch by
Sigmatropic the
following year,
Could That...
-
Ludwig Claisen. The
heating of an
allyl vinyl ether will
initiate a [3,3]-
sigmatropic rearrangement to give a γ,δ-unsaturated carbonyl,
driven by exergonically...
-
uncracked dimer. The
hydrogen atoms in
cyclopentadiene undergo rapid [1,5]-
sigmatropic shifts. The
hydride shift is, however,
sufficiently slow at 0 °C to allow...
- [3,3]-
sigmatropic reaction in the
original report but call it a retro-ene
reaction in
another publication. (Note: The
IUPAC defines a
sigmatropic rearrangement...
-
chorismate to
prephenate in
almost all
prototrophic organisms [1,5]-
sigmatropic shift in the
transformation of precorrin-8x to
hydrogenobyrinic acid...
