- a
scorpionate ligand is a
tridentate (three-donor-site)
ligand that
binds to a
central atom in a fac manner. The most po****r
class of
scorpionates are...
-
react with pot****ium
borohydride to form a
class of
ligands known as
scorpionate.
Pyrazole itself reacts with pot****ium
borohydride at high temperatures...
-
coordination sites available for catalysis. Trofimenko,
Swiatoslaw (1999).
Scorpionates:
Polypyrazolylborate Ligands and
Their Coordination Chemistry. World...
-
Inorganic Chemistry. John Wiley. pp. 140–141. Trofimenko,
Swiatoslaw (1999).
Scorpionates: the
coordination chemistry of
polypyrazolborate ligands (Reprinted. ed...
- generated, such as TpiBuMgCH3.
Trisoxazolinylborate Trofimenko, S., "
Scorpionates: genesis, milestones, prognosis", Polyhedron, 2004, 23, 197-203. doi:10...
-
sometimes bridging Pyrazine N2C4H4
neutral ditopic sometimes bridging Scorpionate ligand tridentate Sulfite O−SO2− 2 S−O2− 3
monoanionic monodentate ambidentate...
- 1002/9780470132432.ch18. ISBN 9780470132432. Trofimenko,
Swiatoslaw (1999).
Scorpionates:
Polypyrazolylborate Ligands and
Their Coordination Chemistry. World...
- Wiencg, J.W; Pruski, M; Sadow, A.D. (2008). "Easily
Prepared Chiral Scorpionates: Tris(2-oxazolinyl)boratoiridium(I)
Compounds and
Their Interactions...
- imidazole-2-thioketone
groups bonded to a
borohydride center. They are
examples of
scorpionate ligands.
Various ligands in this
family are known,
differing in what...
- PMID 21149684. Vidovič C,
Belaj F, Mösch-Zanetti NC (September 2020). "Soft
Scorpionate Hydridotris(2-mercapto-1-methylimidazolyl) borate) Tungsten-Oxido and...
