- In
organic chemistry,
regioselectivity is the
preference of
chemical bonding or
breaking in one
direction over all
other possible directions. It can often...
- of
limonene is to carvone. The three-step
reaction begins with the
regioselective addition of
nitrosyl chloride across the
trisubstituted double bond...
-
charge and
creating the
final alcohol product.
Oxymercuration is very
regioselective and is a
textbook Markovnikov reaction;
ruling out
extreme cases, the...
- ethers,
particularly those with an
adjacent carbonyl group, can be
regioselectively demethylated using magnesium iodide etherate. An
example of this being...
-
Thiol protecting groups used in
peptide synthesis requiring later regioselective disulfide bond
formation must
possess multiple characteristics. First...
- Both electronic/stereoelectronic and
steric factors contribute to the
regioselectivity of 1,3-dipolar cycloadditions. The
dominant electronic interaction...
-
Immobilized Moesziomyces antarcticus lipase can be used to
catalyze the
regioselective acylation of
flavonoids or
direct acylation with
phenolic acids. Moesziomyces...
- Interscience. pp. 350–352. Zimmerman, H. E.; Wang, P. A. (1990). "The
Regioselectivity of the
Birch Reduction". J. Am. Chem. Soc. 112 (3): 1280–1281. doi:10...
-
Sharpless asymmetric dihydroxylation (also
called the
Sharpless bishydroxylation) is the
chemical reaction of an
alkene with
osmium tetroxide in the presence...
- of
carboboration are 1,1 and 1,2 carboboration,
which differ in the
regioselectivity of the
incoming carbon group. 1,1
carboboration delivers both the carbon-carbon...