- In
organic chemistry,
regioselectivity is the
preference of
chemical bonding or
breaking in one
direction over all
other possible directions. It can often...
- Na+, etc.). For
unsymmetrical ketones,
methods exist to
control the
regiochemistry of the deprotonation. The
deprotonation of
carbon acids can proceed...
- In
organic chemistry, free-radical
addition is an
addition reaction which involves free radicals.
These reactions can
happen due to the free
radicals having...
- strongly, and
result in the most
energetically favourable bond formation.
Regiochemistry in
DAINV reactions can be
reliably predicted in many cases. This can...
- An
alkyne trimerisation is a [2+2+2] cycloaddition
reaction in
which three alkyne units (C≡C)
react to form a
benzene ring. The
reaction requires a metal...
- used in the
industrial synthesis of 3-hydroxy-2-naphthoic acid; the
regiochemistry of the
carboxylation in this case is
sensitive to temperature. The Kolbe–Schmitt...
- tris(cyclometallated)
derivative tris(2-phenylpyridine)iridium. The
degree and
regiochemistry of
fluorination of
metalated 2-phenylpyridine
ligands in platinum(II)...
-
component sugars are the same (e.g., glucose),
different bond
combinations (
regiochemistry) and
stereochemistry (alpha- or beta-)
result in
disaccharides that...
-
component sugars are the same (e.g., glucose),
different bond
combinations (
regiochemistry) and
stereochemistry (alpha- or beta-)
result in
trisaccharides that...
-
about the
stereochemistry of the
newly formed alkene, but only the
regiochemistry of the
elimination reaction.
While effective at
predicting the favored...
