Definition of Pummerer. Meaning of Pummerer. Synonyms of Pummerer

- The Pummerer rearrangement is an organic reaction whereby an alkyl sulfoxide rearranges to an α-acyloxy–thioether (monothioacetal-ester) in the presence...
- many cases, the name is merely a mnemonic. Some reactions such as the Pummerer rearrangement, the Pinnick oxidation and the Birch reduction are named...
- anhydride can be used as a dehydrating agent and as an activator for the Pummerer rearrangement. It can be used in place of oxalyl chloride in the Swern...
- α,β-unsaturated ketones (4). β-ketosulfoxides can also be used in the Pummerer rearrangement to introduce nucleophiles alpha to a carbonyl (5). "Sodium...
- acetic anhydride (Ac2O) are used. In this case, the reaction proceeds with Pummerer rearrangement: MTM ethers have another advantage. They are removed by neutral...
- with thionyl chloride. Thionyl chloride can be used in variations of the Pummerer rearrangement. Thionyl chloride converts phosphonic acids and phosphonates...
- photoinitiator. Sulfides can also be prepared by many other methods, such as the Pummerer rearrangement. Trialkysulfonium salts react with nucleophiles with a dialkyl...
- aziridines, and Michael acceptors. They can also be prepared via the Pummerer rearrangement. In the Ferrario reaction, phenyl ether is converted to phenoxathiin...
- Coote; Helen F Sneddon; David J Procter (1 August 2010). "Beyond the Pummerer reaction: recent developments in thionium ion chemistry". Angewandte Chemie...
- Zhen; Pulis, Alexander P; Procter, David J. (2019). "The Interrupted Pummerer Reaction in a Sulfoxide-Catalyzed Oxidative Coupling of 2-Naphthols". Angewandte...