- 350 °C in air. H2PtCl6 →
PtCl2 +
Cl2 + 2 HCl This
method is
convenient since the
chloroplatinic acid is
generated readily from
Pt metal.
Aqueous solutions...
-
forcing filamentous growth of E. coli cells. The
square planar Pt(II) complex, cis-[
PtCl2(NH3)2]
turned out to be even more
effective at
forcing filamentous...
- do not
occur stepwise: (H3O)2PtCl6·nH2O ⇌
PtCl4 + 2 HCl + (n + 2) H2O
PtCl4 ⇌
PtCl2 +
Cl2 PtCl2 ⇌
Pt +
Cl2 All
three reactions are reversible. Platinum(II)...
-
dimerization of trans-[
PtCl2(NCEt)(CO)] with the
production of 2
equivalents of EtCN as a byproduct. To
obtain [
Pt(CO)
Cl2]2, cis-[
PtCl2(NCEt)(CO)] is dissolved...
- is the
trans isomer of the
coordination complex with the
formula trans-
PtCl2(NH3)2,
sometimes called transplatin. It is a
yellow solid with low solubility...
- [(η2-C2H4)
PtCl2]2,
derived from Zeise's salt by
elimination of KCl
followed by dimerisation. COD-platinum dichloride, (cyclooctadiene)
PtCl2,
derived from...
- as a byproduct. The
required PtF5 can be
obtained by
fluorinating PtCl2: 2
PtCl2 + 5 F2 → 2
PtF5 + 2
Cl2 2
PtF5 →
PtF6 +
PtF4
Platinum hexafluoride can...
- chloride:
PtCl42− + 2 PPh3 → cis-
PtCl2(PPh3)2 + 2 Cl− The anti-cancer drug
Cisplatin can
similarly be prepared:
PtCl42− + 2 NH3 → cis-
PtCl2(NH3)2 + 2...
-
cuboidal cluster [
Pt(CH3)3(OH)]4. Upon
heating PtCl4
evolves chlorine to give
PtCl2:
PtCl4 →
PtCl2 +
Cl2 The
heavier halides,
PtBr4 and
PtI4, are also known...
- at the
University of
British Columbia, who
formulated the
product as "Xe+[
PtF6]−",
although subsequent work
suggests that Bartlett's
product was probably...
