Definition of Pseudorotation. Meaning of Pseudorotation. Synonyms of Pseudorotation

- In chemistry, a pseudorotation is a set of intramolecular movements of attached groups (i.e., ligands) on a highly symmetric molecule, leading to a molecule...
- The Berry mechanism, or Berry pseudorotation mechanism, is a type of vibration causing molecules of certain geometries to isomerize by exchanging the two...
- geometry are able to interconvert through a process known as Berry pseudorotation. Pseudorotation is similar in concept to the movement of a conformational diastereomer...
- notably [Ni(CN)5]3−. As a trigonal bipyramidal molecule undergoes Berry pseudorotation, it proceeds via an intermediary stage with the square pyramidal geometry...
- environments. The apparent equivalency arises from the low barrier for pseudorotation via the Berry mechanism, by which the axial and equatorial fluorine...
- Disphenoidal molecules, like trigonal bipyramidal ones, are subject to Berry pseudorotation in which the axial ligands move to equatorial positions and vice versa...
- occurs through tunnelling. This is called hindered pseudorotation. In both free and hindered pseudorotation, the important phenomenon of the geometric (Berry)...
- environments. The apparent equivalency arises from the low barrier for pseudorotation via the Berry mechanism, by which the axial and equatorial fluorine...
- Cruzan; D. D. Lucas; M. G. Brown; K. Liu; R. J. Saykally (1997). "Pseudorotation in Water Trimer Isotopomers Using Terahertz Laser Spectroscopy". J....
- the axial and equatorial F atom positions rapidly interconvert via pseudorotation. At the laboratory scale, sulfur tetrafluoride is prepared from elemental...