-
resemble sulfates. Six-coordinate,
octahedral tungsten dominates in the
polyoxotungstates. In
these compounds, the W–O
distances are elongated. Some examples...
-
tungstate (WO42−). This
oxyanion condenses at
lower pH values,
forming polyoxotungstates. The
broad range of
oxidation states of
tungsten is
reflected in its...
- [MO4]2- precursors. The most
common units for
polymolybdates and
polyoxotungstates are the
octahedral {MO6} centers,
sometimes slightly distorted. Some...
- solutions.
Sodium metatungstate exists as
white solid. The
anion is the
polyoxotungstate [H2W12O40]6-,
which features six-coordinated tungsten(VI)
centers interconnected...
- PMID 16676943. B****il, B****em S.; Kortz,
Ulrich (2011). "Divacant
polyoxotungstates:
Reactivity of the gamma-decatungstates [γ-XW10O36]8−(X = Si, Ge)"...
-
organometallic polymetallic species, and
finally the
chemistry of
polyoxotungstates. In the
latter case, it is
essentially the
compounds containing the...
