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Polymethylhydrosiloxane (PMHS) is a
polymer with the
general structure [−CH3(H)Si−O−]. It is used in
organic chemistry as a mild and
stable reducing agent...
- The
compound is
produced by
reduction of
tributyltin oxide with
polymethylhydrosiloxane: 2 "[MeSi(H)O]n" + (Bu3Sn)2O → "[MeSi(OH)O]n" + 2 Bu3SnH It can...
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phenyl chlorothionoformate and then
tributylstannic oxide and
polymethylhydrosiloxane. The
thiobenzoyl radical intermediates formed when the
ester homolyzes...
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Burgess reagent oxidation with p-chloranil
dehalogenation with
polymethylhydrosiloxane, palladium(II) acetate, pot****ium
phosphate and the DPDB ligand...
- phenyl.
Examples include polydimethylsiloxane (PDMS, [Me2SiO]n),
polymethylhydrosiloxane (PMHS, [MeSi(H)O]n) and
polydiphenylsiloxane [Ph2SiO]n). Related...
- by
various clays. (3-Aminopropyl)triethoxysilane
Cyclomethicone Polymethylhydrosiloxane (PMHS)
Silicone rubber Silicone Siloxane,
Cyclosiloxane and other...
- PMHS may
refer to:
Polymethylhydrosiloxane Parramatta Marist High School, Westmead, New
South Wales,
Australia Parry McCluer High School,
Buena Vista...
- dechlorination:
reductive dechlorination of
polychlorobiphenyls by
polymethylhydrosiloxane-alkali metal. J. Organomet. Chem. 1992, 437, 91-98. Mackenzie,...
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Intermolecular Regioselective Hydroamination of
Styrenes with
Polymethylhydrosiloxane and Hydroxylamines". Angew. Chem. Int. Ed. 52 (41): 10830–10834...
- required.
Aldehydes and
ketones Polymeric hydrosilanes, such as
polymethylhydrosiloxane (PHMS), may be emplo**** to
facilitate separation of the reduced...
