-
Polycarbonyl, (also
known as polymeric-CO, p-CO or poly-CO) is a solid, metastable, and
explosive polymer of
carbon monoxide. The
polymer is
produced by...
- monoxide. At
pressures exceeding 5 GPa,
carbon monoxide converts to
polycarbonyl, a
solid polymer that is
metastable at
atmospheric pressure but is explosive...
- 1021/jp010738i. Rubin, M. B.; Gleiter, R. (2000). "The
Chemistry of
Vicinal Polycarbonyl Compounds".
Chemical Reviews. 100 (3): 1121–1164. doi:10.1021/cr960079j...
-
member being Cr(NO)4. Even
trinitrosyl complexes are uncommon,
whereas polycarbonyl complexes are routine. One of the
earliest examples of a
nitrosyl complex...
-
about the
structure and
composition of the complexes.
Spectra for
metal polycarbonyls are
often easily interpretable,
because the
dominant fragmentation process...
- Information. Rubin, M. B.; Gleiter, R. (2000). "The
Chemistry of
Vicinal Polycarbonyl Compounds".
Chemical Reviews. 100 (3): 1121–64. doi:10.1021/cr960079j...
- Delderfield, G.A. Webb (1968). "A m****
spectrometric study of some
monocyclic polycarbonyl compounds". Tetrahedron. 24 (13): 4805–4817. doi:10.1016/S0040-4020(01)98676-4...
- Freedlander, B.L.; French,
Frederic A. (1958). "Carcinostatic
Action of
Polycarbonyl Compounds and
Their Derivatives II.
Glyoxal Bis(Guanylhydrazone) and...
-
transition metals in
organic synthesis. He
found a new
method for
alkylating polycarbonyl compounds using palladium catalysis in
neutral media.
Apart from advancing...
- and
fluid oxygen. High
pressure carbon monoxide forms the high
energy polycarbonyl covalent solid,
however it is not
expected to be
present inside the Earth...