-
organophosphorus compound,
phosphirene is the
prototype of a
family of
related compounds that have
attracted attention from researchers.
Phosphirenes, that is substituted...
-
Oxygen Oxirane (ethylene oxide, epoxides)
Oxirene Phosphorus Phosphirane Phosphirene Sulfur Thiirane (ethylene sulfide, episulfides)
Thiirene Three-membered...
-
phosphetene was
reported in 1985 by
Mathey et al. via ring
expansion of a
phosphirene-metal
carbonyl complex.
Since then,
other synthesis routes for phosphetenes...
- with the
conjugate base of phosphine. Phosphiranes, that is
substituted phosphirene compounds where one or more of the H's are
replaced organic substituents...
-
through a 3-center-2-electron bond. tBu2C2P2 can be used a
retron to form
phosphirenes or
phosphaalkenes with the
addition of 1
equivalent or 2 equivalents...
- 1-Methylcyclopropene (1-MCP) is used to slow the
ripening in fruits. Borirenes,
phosphirenes, and
silirenes are boron-, phosphorus-, and silicon-substituted cyclopropenes...
- Oliver; Ehle, Michael; Regitz,
Manfred (1989). "2-Chloro-2H-
phosphirene/1-Chloro-1H-
phosphirene Isomerization by [1,3]-Chlorine Shift".
Angewandte Chemie...
- in
cyclic forms. Three-membered
rings are
phosphiranes (unsaturated:
phosphirenes), five-membered
rings are
phospholanes (unsaturated: phosphole), and...
-
phosphinidene complexes.
Synthesis and x-ray
crystal structure of
stable phosphirene complexes".
Journal of the
American Chemical Society. 104 (16): 4484–4485...
- [2+1]-cycloaddition
reactions between phosphaalkynes and
chlorocarbene give
phosphirenes,
which serve as
starting materials for the
generation of phosphirenium...
