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Phosphinous acids are
usually organophosphorus compounds with the
formula R2POH. They are
pyramidal in structure.
Phosphorus is in the
oxidation state...
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Phosphinous acid is the
inorganic compound with the
formula H2POH. It exists, fleetingly, as a
mixture with its less
stable tautomer H3PO (phosphine oxide)...
- diphenylphosphinite: ClPPh2 + CH3OH → CH3OPPh2 + HCl
Although they are
esters of
phosphinous acids (R2POH),
phosphinites are not made via such intermediates. Oxidation...
- Hydroxy(oxo)-λ5-phosphane Hydroxy-λ5-phosphanone Oxo-λ5-phosphanol Oxo-λ5-
phosphinous acid
Phosphonous acid (for
minor tautomer)
Identifiers CAS
Number 6303-21-5 Y...
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arise via
alcoholysis reactions of the
corresponding phosphonous and
phosphinous chlorides ((PCl2R') and (PClR'2) , respectively). The
latter are produced...
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Carmen López-Leonardo;
Pilar Llamas-Lorente (2005). "The
Chemistry of
Phosphinous Amides (Aminophosphanes): Old
Reagents with New Applications". Top. Curr...
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Chlorodiisopropylphosphine Names Preferred IUPAC name Di(propan-2-yl)
phosphinous chloride Identifiers CAS
Number 40244-90-4 3D
model (JSmol) Interactive...
- 1021/jo070855v, PMID 17585827 Wolf, C.; Lerebours, R. (2004), "Palladium−
Phosphinous Acid-Catalyzed NaOH-Promoted Cross-Coupling
Reactions of Arylsiloxanes...
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bonds formed by MX (M═Cu, Ag, Au; X═F, Cl, Br) with phosphine-oxide/
phosphinous acid:
comparisons between oxygen-shared and phosphine-shared complexes"...
- R2P(O)OH + H2O
These reactions are
preceded by
tautomerization to the
phosphinous acid (R2POH): R2P(O)H ↽ − ⇀ {\displaystyle {\ce {<<=>}}} R2POH Primary...
