-
generate and
transfer phosphinidenes as
intermediates in the
synthesis of
various organophosphorus compounds. Like carbenes,
phosphinidenes can
exist in either...
- 4-coordinate silicon,
which can also be
viewed as silylene-stabilized
phosphinidene, can be
synthesized based on the
reactivities of
stable silyene complexes...
-
Carbenoid Ion-neutral
complex Keto
anions Nitrenes Oxocarbenium ions
Phosphinidenes Phosphoryl nitride Tetrahedral intermediates in
carbonyl addition reactions...
-
recent synthesis reported in 2019
proceeds through the
transfer of a
phosphinidene species from dibenzo-7-(R)-7-phospha-norbornadiene (RPA) onto styrene...
- chemistry;
especially their use in
stabilizing carbenes, nitrenes,
phosphinidenes,
radicals and biradicals, 1,3-dipoles, anti-aromatic heterocycles, and...
-
reacting with main-group
starting materials such as ylides, silylene, and
phosphinidene to
synthesize and
isolate for
further steps. As CO
becomes a more common...
- Wolczanski,
Peter T.; Lobkovsky, Emil B. (1994-11-01). "Arsinidene,
Phosphinidene, and
Imide Formation via 1,2-H2-Elimination from (silox)3HTaEHPh (E...
-
University of
Chicago Thesis The
chemistry of three-coordinate
nickel phosphinidene, imido, and
carbene complexes (2004)
Doctoral advisor Gregory L. Hillhouse...
- R2N+ (protonated nitrenes)
phosphinidenium cations, R2P+ (protonated
phosphinidene)
mercurinium cations, R3Hg+ (protonated
organomercury compounds; formed...
- phosphanido, or dihydridophosphato(1−). A
related substance has PH2−.
Phosphinidene (PH) has
phosphorus in a −1
oxidation state. As a
ligand PH2 can either...
