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Phosphinidenes (IUPAC: phosphanylidenes,
formerly phosphinediyls) are low-valent
phosphorus compounds analogous to
carbenes and nitrenes,
having the general...
- 4-coordinate silicon,
which can also be
viewed as silylene-stabilized
phosphinidene, can be
synthesized based on the
reactivities of
stable silyene complexes...
- Wolczanski,
Peter T.; Lobkovsky, Emil B. (1994-11-01). "Arsinidene,
Phosphinidene, and
Imide Formation via 1,2-H2-Elimination from (silox)3HTaEHPh (E...
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recent synthesis reported in 2019
proceeds through the
transfer of a
phosphinidene species from dibenzo-7-(R)-7-phospha-norbornadiene (RPA) onto styrene...
- phosphanido, or dihydridophosphato(1−). A
related substance has PH2−.
Phosphinidene (PH) has
phosphorus in a −1
oxidation state. As a
ligand PH2 can either...
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reacting with main-group
starting materials such as ylides, silylene, and
phosphinidene to
synthesize and
isolate for
further steps. As CO
becomes a more common...
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monomeric intermediate fragment. The V-NP
fragment undergoes singlet phosphinidene reactivity ([2+1] additions) with
alkene and
alkyne trapping agents...
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proceed via
metal phosphido intermediates. Some
however proceed by metal-
phosphinidene intermediates, i.e.
species with M=PR
double bonds. One such example...
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Daniel J.; Hillhouse,
Gregory L. (2002). "Monomeric
Phosphido and
Phosphinidene Complexes of Nickel".
Journal of the
American Chemical Society. 124...
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Carbenoid Ion-neutral
complex Keto
anions Nitrenes Oxocarbenium ions
Phosphinidenes Phosphoryl nitride Tetrahedral intermediates in
carbonyl addition reactions...
