- A
transition metal phosphido complex is a
coordination complex containing a
phosphido ligand (R2P,
where R = H,
organic substituent). With two lone pairs...
-
containing the [PH2]− anion. This is also
known as the
phosphino anion or
phosphido ligand. The
IUPAC name can also be dihydridophosphate(1−). It can occur...
-
inorganic ligands (R = alkyl, aryl): OR−, SR−, NR−2, NR2− (imido), PR−2 (
phosphido, note the
ambiguity with the
preceding entry), PR2− (phosphinidino), and...
-
Structure of
terminal phosphido complexes of Mo....
- ; Atwood, J. L.; Bott, S. G. (1993). "Cyclic
Trimeric Hydroxy, Amido,
Phosphido, and ****nido
Derivatives of
aluminum and gallium. X-ray
Structures of...
- L.; Hibbs, D. E.; Jones, C.; Smithies, N. A. (2000). "Phosphine and
phosphido indium hydride complexes and
their use in
inorganic synthesis". Journal...
-
being an
unsaturated π-ligand,
having their own reactivity. The
first phosphido derivative of
tantalocene was
obtained by the
insertion of ClPPh2 into...
-
metathesis with the bis(trimethylsilyl)methylene
ligand forming the lanthanide-
phosphido complex. Subsequently, the
pendant terminal alkene or
alkyne inserts into...
- Mina; Strianese, Maria; Kühl, Olaf; Peters,
Jonas C. (2011-08-23). "
Phosphido pincer complexes of platinum: synthesis,
structure and reactivity". Dalton...
- KP(SiMe3)2 + Me3SiO-t-Bu It is a
reagent in the
preparation of
metal phosphido clusters by
reaction with
metal halides or carboxylates. In such reactions...
