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Phosphanides are
chemicals containing the [PH2]− anion. This is also
known as the
phosphino anion or
phosphido ligand. The
IUPAC name can also be dihydridophosphate(1−)...
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Ammonia Structure Molecular shape Bent
Related compounds Other anions Phosphanide Arsinide Imide Nitride Nitridohydride Related isoelectronic water, fluoronium...
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exchange proceeds via a
phosphonium (PH+4) ion in
acidic solutions and via
phosphanide (PH−2) at high pH, with
equilibrium constants Kb = 4×10−28 and Ka = 41...
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through sequential phosphanide/phosphine
displacement of 1,3-alkyl
dihalides or
sulfonate esters (OTf, OTs, OMs, etc.). The
phosphanide source is commonly...
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Structures of
Sterically Congested Sodium and
Cesium Silyl(fluorosilyl)
phosphanide Aggregates and
Structural Characterization of the
Trimeric Sodium...
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selenium analog of
hydroxide Azanide, a
nitrogen analog of
hydroxide Phosphanide, a
phosphorus analog of
hydroxide and
azanide Arsanide, an ****nic analog...
- phph PH2, a
postcode in Perth, Scotland, see PH
postcode area PH2− the
phosphanide ion in
inorganic chemistry -PH2 the
phosphanyl group in
organic chemistry...
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structure of pot****ium
phosphide (K3P)
Names Other names Tripot****ium;
phosphanide Tripot****ium;phosphorus(3-) Tripot****ium
phosphide Identifiers CAS Number...
- (2010-05-17). "Germanium(II) and Tin(II)
Complexes of a
Sterically Demanding Phosphanide Ligand".
Inorganic Chemistry. 49 (10): 4698–4707. doi:10.1021/ic1003534...
- the
scheme on the left, it is also
possible to use pre-formed
lithium phosphanides Ar'P(H)Li as both a
phosphorus source and a base. However, the latter...
