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hydrogen atoms with
organic groups. They have the
general formula PH3−nRn.
Phosphanes are
saturated phosphorus hydrides of the form PnHn+2, such as triphosphane...
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where nitrogen act as a
proton acceptor.
These include the phosphazenes,
phosphanes, amidines, and guanidines.
Other organic compounds that meet the physicochemical...
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polyphosphane series are known, from PnHn to PnHn−18,
amounting to 85
known phosphanes in 1997.
Noncyclic hydrogen pnictides follow the
formula XnHn+2. Ammonia...
- A metal-phosphine
complex is a
coordination complex containing one or more
phosphine ligands.
Almost always, the
phosphine is an
organophosphine of the...
-
polarizability plays a role as well. This can also
explain why
phosphorus in
phosphanes can't
donate electron density to
carbon through induction (i.e. +I effect)...
- and 'tetracarbane' as
recommended for
analogues of silane, 'disilane';
phosphane, 'triphosphane'; and sulfane, 'tetrasulfane'. W. B. Kay (1940)....
-
preparation of
organic phosphines with the
formula R3P (sometimes
called phosphanes) such as triphenylphosphine, Ph3P. 3
RMgBr + PCl3 → R3P + 3
MgBrCl Triphenylphosphine...
- Kristjan; Saame, Jaan; Kütt, Agnes; Leito, Ivo (2012). "Basicity of
Phosphanes and
Diphosphanes in Acetonitrile".
European Journal of
Organic Chemistry...
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Phosphanes PH3 P2H4 P3H5 P4H6 P5H7 P6H8 P7H9 P8H10 P9H11 P10H12 more......
- to form
pnictogen hydrides such as ammonia.
Going down the group, to
phosphane (phosphine),
arsane (arsine),
stibane (stibine), and
finally bis****ne...