-
variety of
kinetically stable phosphaalkynes,
including aryl,
tertiary alkyl,
secondary alkyl, and even
primary alkyl phosphaalkynes in good yields. Dihalophospaalkenes...
- phosphorus(III)
multiple bonds are
called phosphaalkenes (R2C=PR) and
phosphaalkynes (RC≡P). They are
similar in structure, but not in reactivity, to imines...
-
closest approach is the half-phosphorus
compound P4(CH)4,
produced from
phosphaalkynes.
Other clusters are more
thermodynamically favorable, and some have...
- of
phosphaalkynes. Such
isomeric species have
never been isolated. With
their characteristic C-P
triple bonds, the
phosphorus atoms of
phosphaalkynes such...
-
Phosphonous Phosphinate Phosphine oxide Phosphine Phosphonium Phosphaalkene Phosphaalkyne Phosphaallene Sulfur Thiol Sulfide Sulfonium Persulfide Disulfide Sulfenic...
-
Phosphonous Phosphinate Phosphine oxide Phosphine Phosphonium Phosphaalkene Phosphaalkyne Phosphaallene Sulfur Thiol Sulfide Sulfonium Persulfide Disulfide Sulfenic...
-
closest approach is the half-phosphorus
compound P4(CH)4,
produced from
phosphaalkynes.
Other clusters are more
thermodynamically favorable, and some have...
-
preparations use two
other routes:
Treatment of the η1-coordinated
phosphaalkyne complex trans–[RuH(P≡CSiPh3)(dppe)2]+ with an
alkoxide resulted in desilylation...
-
Phosphonous Phosphinate Phosphine oxide Phosphine Phosphonium Phosphaalkene Phosphaalkyne Phosphaallene Sulfur Thiol Sulfide Sulfonium Persulfide Disulfide Sulfenic...
- of
certain acyl
chlorides with tris(trimethylsilyl)phosphine
gives phosphaalkynes, one
example being tert-butylphosphaacetylene.
Reaction with pot****ium...
