-
Phenyllithium is an
organometallic agent with the
empirical formula C6H5Li. It is most
commonly used as a
metalating agent in
organic syntheses and a...
-
chloride and
phenyllithium,
which functions as a base:
Methallyl chloride Phenyl lithium (base) LiCl + PhH 1-Methylcyclopropene The
phenyllithium should...
- give di-, tri-, and
tetrasulfonic acids.
Analogous to the
synthesis of
phenyllithium is the
conversion of 1-bromonaphthalene to 1-lithionaphthalene, by lithium–halogen...
-
treatment of
phosphorus trichloride with
phenylmagnesium bromide or
phenyllithium. The
industrial synthesis involves the
reaction between phosphorus trichloride...
- as
solvent in
various chemical reactions and processes. For example,
phenyllithium is
commercially available as a ca. 1.8M
solution in
dibutyl ether. Because...
- Dinnebier, R. E.; Behrens, U.; Olbrich, F. (1998). "Lewis Base-Free
Phenyllithium:
Determination of the Solid-State
Structure by
Synchrotron Powder Diffraction"...
-
starting material A more
modern synthesis involves the
reaction of
phenyllithium and NaOtBu: C6H5Li +
NaOtBu → C6H5Na +
LiOtBu The
first syntheses of...
-
phenyl anion or the
phenyl cation.
Representative reagents include phenyllithium (C6H5Li) and
phenylmagnesium bromide (C6H5MgBr).
Electrophiles are attacked...
- n-butyllithium and form
solvated dimers such as [(TMEDA) LiBu-n)]2.
Phenyllithium has been
shown to
exist as a
distorted tetramer in the crystallized...
- N-dimethylformamide (DMF) can be used to
introduce a
formyl group. Here,
phenyllithium 1
attacks the
carbonyl group of DMF 2,
giving tetrahedral intermediate...
