- The
Bamberger rearrangement is the
chemical reaction of
phenylhydroxylamines with
strong aqueous acid,
which will
rearrange to give 4-aminophenols. It...
- C6H5NH2 and C6H5NO. N-
Phenylhydroxylamine should not be
confused with its
isomer α-
phenylhydroxylamine or O-
phenylhydroxylamine. This
compound can be...
-
rearrangement of
esters in the
Fries rearrangement rearrangement of N-
phenylhydroxylamines in the
Bamberger rearrangement dealkylation of
phenolic ethers reduction...
- the
ammonium salt of the
conjugate base
derived from N-nitroso-N-
phenylhydroxylamine. This
conjugate base is
abbreviated as CU−. It once was a common...
-
methemoglobinemia is
produced in
humans mainly by
another metabolite,
phenylhydroxylamine. A follow-up
paper by
Brodie and
Axelrod in 1949
established that...
- to azoxybenzene, azobenzene, nitrosobenzene, hydrazobenzene, and
phenylhydroxylamine. It has been used as a mild
oxidant in
reactions like the Skraup...
-
reactions on
arenes are
listed below. In the
Bamberger rearrangement N-
phenylhydroxylamines rearrange to 4-aminophenols. The
nucleophile is water. The Smiles...
-
phenols and aryl
sulfonamides n-Butyl
nitrite and
ammonia convert phenylhydroxylamine to its
nitrosamine derivative cupferron.
Likewise pyrrolidine is...
- Alternatively, the
partial hydrogenation of
nitrobenzene affords phenylhydroxylamine,
which rearranges primarily to 4-aminophenol (Bamberger rearrangement)...
- Syntheses;
Collected Volumes, vol. 4, p. 148. Kamm, O. (1941). "β-
Phenylhydroxylamine".
Organic Syntheses;
Collected Volumes, vol. 1, p. 445. Ichikawa...
