-
Periodinanes also
known as λ5-iodanes are
organoiodine compounds with
iodine in the +5
oxidation state.
These compounds are
described as
hypervalent because...
- Dess–Martin
periodinane (DMP) is a
chemical reagent used in the Dess–Martin oxidation,
oxidizing primary alcohols to
aldehydes and
secondary alcohols...
-
organic compound used in
organic synthesis as an
oxidizing agent. This
periodinane is
especially suited to
oxidize alcohols to aldehydes. IBX is most often...
- Dess–Martin
periodinane. It is
named after the
American chemists Daniel Benjamin Dess and
James Cullen Martin who
developed the
periodinane reagent in...
-
common uses is as a
precursor for the
preparation of IBX and Dess–Martin
periodinane, both used as mild oxidants. 2-Iodobenzoic acid can be
synthesized by...
-
oxidation Albright-Goldman
oxidation Corey–Kim
oxidation Dess–Martin
periodinane oxidation Ley
oxidation (TPAP oxidation)
TEMPO oxidation Omura, K.; Swern...
- or a Cr(VI) compound.
Milder conditions make use of the Dess–Martin
periodinane or the Moffatt–Swern methods. Many
other methods have been developed...
- the
hypervalent organoiodine compounds (i.e., IBX acid, Dess–Martin
periodinane),
although these often also
oxidize the α position. A Lux-Flood acid...
- oxidations, and
hypervalent iodine compounds, such as the Dess–Martin
periodinane. One
disadvantage to the use of PCC is its toxicity,
which it shares...
-
October 2017.
Boeckman Jr RK, Shao P,
Mullins JJ (2000). "Dess–Martin
periodinane: 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one".
Organic Syntheses...
