-
peroxy acid (often
spelled as one word, peroxyacid, and
sometimes called peracid) is an acid
which contains an
acidic −OOH group. The two main
classes are...
-
peracid is
intramolecularly hydrogen-bonded at the
transition state.
Although there are
frontier orbital interactions in both directions, the
peracid...
- (Z)-3-ureidoacrylate
peracid amidohydrolase. This
enzyme catalyses the
following chemical reaction sequences: (Z)-3-ureidoacrylate
peracid + H2O ⇌ (Z)-3-peroxyaminoacrylate...
-
water to
produce peracetic acid.
Although less
active than more
acidic peracids (e.g., m-CPBA),
peracetic acid in
various forms is used for the epoxidation...
-
reaction is
given below: The
geometry of the
transition state, with the
peracid bisecting the C-C
double bond,
allows the two
primary frontier orbital...
-
epoxy resins is the
conversion of
aliphatic or
cycloaliphatic alkenes with
peracids: In
contrast to glycidyl-based
epoxy resins, this
production of such epoxy...
-
internal alkene, isoapiole,
followed by a
peracid oxidation and
finally a
hydrolytic dehydration. The
peracid oxidation can be
accomplished by combining...
- formation.
Carbon attack was
suggested by
Rudolf Criegee. In this pathway, the
peracid attacks the
carbonyl carbon,
producing what is now
known as the Criegee...
- as a 69–70%
aqueous solution.
Compared to
hydrogen peroxide and
organic peracids, tert-butyl
hydroperoxide is less
reactive and more
soluble in organic...
- out with the iodine-starch reaction. Here peroxides,
hydroperoxides or
peracids oxidize the
added pot****ium
iodide into iodine,
which reacts with starch...
