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Pentacarbonylhydridorhenium is a
chemical compound with the
formula ReH(CO)5. This
colorless liquid is a weak acid and
represents one of the most important...
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Reduction of this
pentacarbonyl with zinc and
acetic acid
gives pentacarbonylhydridorhenium: Re(CO)5Br + Zn + HOAc → Re(CO)5H + ZnBr(OAc)
Methylrhenium trioxide...
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rhenium complexes. It
reacts with zinc and
acetic acid to give
pentacarbonylhydridorhenium (HRe(CO)5). Re(CO)5Br + Zn + HO2CCH3 → ReH(CO)5 + ZnBrO2CCH3...
-
Reduction of this
pentacarbonyl with zinc and
acetic acid
gives pentacarbonylhydridorhenium: Re(CO)5Br + Zn + HOAc → Re(CO)5H + ZnBr(OAc)
Methylrhenium trioxide...
- bromopentacarbonylrhenium(I), then
reduced with zinc and
acetic acid to
pentacarbonylhydridorhenium: Re2(CO)10 + Br2 → 2 Re(CO)5Br Re(CO)5Br + Zn + HOAc → Re(CO)5H...
- bromopentacarbonylrhenium(I), then
reduced with zinc and
acetic acid to
pentacarbonylhydridorhenium: Re2(CO)10 + Br2 → 2 Re(CO)5Br Re(CO)5Br + Zn + HOAc → Re(CO)5H...
