- the
coordinating ligands, the
neutral palladacycles can be monomers, dimers, or bis-cyclopalladated.
Palladacycles with ring-sizes
range from 3 to 10 have...
- Many
analogues of Hermann's
catalyst have been developed, e.g.
palladacycles obtained from 2-aminobiphenyl. Herrmann, W. A.; Brossmer, C.; Reisinger...
- Reisinger, C.-P.; Riermeier, T. H.; Öfele, K.; Beller, M. (1997). "
Palladacycles:
Efficient New
Catalysts for the Heck
Vinylation of Aryl Halides". Chemistry...
- Palladium-Catalyzed
Synthesis of
Methyl Aryl
Ethers Enabled by the Use of a
Palladacycle Precatalyst".
Organic Letters. 15 (15): 3998–4001. doi:10.1021/ol401796v...
- Reisinger, C.-P.; Riermeier, T. H.; Öfele, K.; Beller, M. (1997). "
Palladacycles:
Efficient New
Catalysts for the Heck
Vinylation of Aryl Halides". Chemistry...
-
colorless solid,
although aged
samples can
appear colored even black.
Palladacycles obtained from 2-aminobiphenyl are po****r
catalysts for cross-coupling...
- Reisinger, C.-P.; Riermeier, T. H.; Öfele, K.; Beller, M. (1997). "
Palladacycles:
Efficient New
Catalysts for the Heck
Vinylation of Aryl Halides". Chemistry...
-
General Conditions for
Negishi Cross-Coupling
Enabled by the Use of
Palladacycle Precatalysts". Angew. Chem. Int. Ed. 52 (2): 615–619. doi:10.1002/anie...
-
Aminoboration of
Alkenyl Carbonyl Compounds via Five- and Six-Membered
Palladacycles".
Journal of the
American Chemical Society. 140 (9): 3223–3227. doi:10...
- anti-Markovnikov
carbon to
generate the more
thermodynamically stable palladacycle. Anti-Markovnikov
selectivity is also
observed in
styrenyl substrates...
