Definition of Oxymercuration. Meaning of Oxymercuration. Synonyms of Oxymercuration

- the oxymercuration reaction is an electrophilic addition reaction that transforms an alkene (R2C=CR2) into a neutral alcohol. In oxymercuration, the...
- to other hydration reactions such as acid-catalyzed addition and the oxymercuration–reduction process. The reaction was first reported by Herbert C. Brown...
- Hydrohalogenations: HX Hydration reactions: H2O Hydrogenations: H2 Oxymercuration reactions: mercuric acetate, water Hydroboration-oxidation reactions:...
- the hydroxyl group attaches to the more substituted carbon. Alkene oxymercuration-demercuration Stereospecific: Can only be anti addition – water kicks...
- producing alcohols, including the hydroboration–oxidation reaction, the oxymercuration–reduction reaction, the Mukaiyama hydration, the reduction of ketones...
- Hg(OAc)2 → (RS)2C=O + HgS + 2 HOAc Mercury(II) acetate is used for oxymercuration reactions. A famous use of Hg(OAc)2 was in the synthesis of idoxuridine...
- alkene reduction and hydration is shown: The hydroboration-oxidation and oxymercuration-reduction of alkenes are more reliable in organic synthesis. Alkenes...
- Hydroboration–oxidation alcohols reagents: borane, then a peroxide Oxymercuration-reduction alcohols electrophilic addition of mercuric acetate, then...
- Oxidation Oxidative addition Oxidative decarbonylation Oxygenation Oxymercuration reaction Pauson–Khand reaction Photodissociation Pseudorotation Protonation...
- mercury sulfate and mercury(II) acetate are commonly used as catalysts in oxymercuration-demercuration, a type of electrophilic addition reaction which results...