- In
their largest application,
oxaziridines are
intermediates in the
industrial production of hydrazine.
Oxaziridine derivatives are also used as specialized...
- the
active dioxirane form
before proceeding in the
catalytic cycle.
Oxaziridines such as
chiral N-sulfonyloxaziridines
effect enantioselective ketone...
-
hydrogen peroxide to the
oxaziridine, a three-membered ring
containing carbon, oxygen, and nitrogen. Next, the
oxaziridine gives the
hydrazone by treatment...
-
deficient oxygen of the
oxaziridine ring. This
reaction type is
extended to
asymmetric synthesis by the use of
chiral oxaziridines derived from
camphor (camphorsulfonyl...
-
reactivity may be
reversed for some electron-deficient amines,
including oxaziridines, hydroxylamines, oximes, and
other N–O substrates. When the
amine is...
-
Davis reagent (3-phenyl-2-(phenylsulfonyl)-1,2-
oxaziridine or 2-(benzenesulfonyl)-3-phenyloxaziridine) is a
reagent used for
oxidation in the
Davis oxidation...
- electron-withdrawing groups: chloramines, hydroxylamines, hydrazines, and
oxaziridines, for instance.
Addition reactions have emplo**** imines, oximes, azides...
- (1992). "Chemistry of
oxaziridines. 18.
Synthesis and
enantioselective oxidations of the [(8,8-dihalocamphoryl)sulfonyl]
oxaziridines". The
Journal of Organic...
- H2O
Oxidation of the
imine to the
oxaziridine: Me(Et)C=NH + H2O2 → Me(Et)CONH + H2O
Condensation of the
oxaziridine with a
second molecule of ammonia...
-
Imine are
oxidized with meta-chloroperoxybenzoic acid (mCPBA) to give an
oxaziridines.
Imines are
intermediates in the
alkylation of
amines with
formic acid...
