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Trimethyl orthoformate (TMOF) is the
organic compound with the
formula HC(OCH3)3. A
colorless liquid, it is the
simplest orthoester. It is a
reagent used...
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Triethyl orthoformate is an
organic compound with the
formula HC(OC2H5)3. This
colorless volatile liquid, the
ortho ester of
formic acid, is commercially...
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yields the triply-bridged
orthoformate esters scyllitol orthoformate with an adamantane-like skeleton, and
scyllitol bis-
orthoformate with two
fused adamantane-like...
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frozen mixture of
methanol and oxygen.
Methanetriol esters,
known as
orthoformates or
ortho esters, are well
known and
commercially available. Like acetals...
- formate, CH3(HCOO)
methyl chloroformate, CH3OCOCl
triethyl orthoformate trimethyl orthoformate, C4H10O3
phenyl formate HCOOC6H5 amyl
formate Reutemann,...
- or inorganic) and R′
stands for
organyl group. For example,
triethyl orthoformate (HC(OCH2CH3)3) is derived, in
terms of its name (but not its synthesis)...
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carbonyl group at C3 is then
transformed to
dienol ethyl ether using ethyl orthoformate. The
obtained product is
ethynylated by
acetylene in the
presence of...
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aldehyde one
carbon longer.
Reaction of a
Grignard reagent with
triethyl orthoformate gives an acetal,
which can be
hydrolyzed to an aldehyde. For example...
- of o-phenylenediamine with
formic acid, or the
equivalent trimethyl orthoformate: C6H4(NH2)2 + HC(OCH3)3 → C6H4N(NH)CH + 3 CH3OH 2-Substituted derivatives...
-
tetrahalomethanes does not
yield the
desired product,
instead giving orthoformates and a
halohydrin byproduct.: 13  The
original preparation of the tetramethoxymethane...
