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Trimethyl orthoformate (TMOF) is the
organic compound with the
formula HC(OCH3)3. A
colorless liquid, it is the
simplest orthoester. It is a
reagent used...
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Triethyl orthoformate is an
organic compound with the
formula HC(OC2H5)3. This
colorless volatile liquid, the
ortho ester of
formic acid, is commercially...
-
yields the triply-bridged
orthoformate esters scyllitol orthoformate with an adamantane-like skeleton, and
scyllitol bis-
orthoformate with two
fused adamantane-like...
- this
product with
methyl orthoformate in the
presence of a base
leads to the
replacement of the
alkoxy groups in
orthoformate by the
adjacent amines, resulting...
- formate, CH3(HCOO)
methyl chloroformate, CH3OCOCl
triethyl orthoformate trimethyl orthoformate, C4H10O3
phenyl formate HCOOC6H5 amyl
formate Reutemann,...
- agents.
Especially well
known are
trimethyl orthoformate,
triethyl orthoformate, and
triisopropyl orthoformate.
Methanol Methanediol Orthoacetic acid Orthocarbonic...
- of o-phenylenediamine with
formic acid, or the
equivalent trimethyl orthoformate: C6H4(NH2)2 + HC(OCH3)3 → C6H4N(NH)CH + 3 CH3OH 2-Substituted derivatives...
- or inorganic) and R′
stands for
organyl group. For example,
triethyl orthoformate (HC(OCH2CH3)3) is derived, in
terms of its name (but not its synthesis)...
-
aldehyde one
carbon longer.
Reaction of a
Grignard reagent with
triethyl orthoformate gives an acetal,
which can be
hydrolyzed to an aldehyde. For example...
-
sulfuric acid.
Additional reaction steps,
alcohol protection with
methyl orthoformate and
boron trifluoride) and then
ketone reduction with
sodium borohydride...
