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Organozinc chemistry is the
study of the
physical properties, synthesis, and
reactions of
organozinc compounds,
which are
organometallic compounds that...
- cross-coupling reaction. The
reaction couples organic halides or
triflates with
organozinc compounds,
forming carbon-carbon
bonds (C-C) in the process. A palladium...
- and
lacking acidic protons, this
complex is used in the
synthesis of
organozinc compounds. A
related 1:2
complex is ZnCl2(NH2OH)2 (zinc
dichloride di(hydroxylamine))...
- Simmons–Smith
reaction is an
organic cheletropic reaction involving an
organozinc carbenoid that
reacts with an
alkene (or alkyne) to form a cyclopropane...
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Organozincs have
similar reactivity to
Grignard reagents but are much less nucleophilic, and they are
expensive and
difficult to handle.
Organozincs typically...
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Diethylzinc (C2H5)2Zn, or DEZ, is a
highly pyrophoric and
reactive organozinc compound consisting of a zinc
center bound to two
ethyl groups. This colourless...
- at
elevated temperatures,
whereas the
corresponding organocadmium and
organozinc compounds (and most
metal alkyls in general)
hydrolyze rapidly. The difference...
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application as an
activated source of zinc
required for
formation of an
organozinc reagent in the Simmons–Smith
cyclopropanation of alkenes. The
couple has...
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usually two-coordinate and
linear geometry.
Unlike organocadmium and
organozinc compounds,
organomercury compounds do not
react with water. They usually...
-
compounds include organolithium compounds such as n-butyllithium (n-BuLi),
organozinc compounds such as
diethylzinc (Et2Zn),
organotin compounds such as tributyltin...
