- (CH3)4-xSiClx.
Another important member is
trichlorosilane (SiHCl 3).
Organosilanes are a
class of charge-neutral
organosilicon compounds. Example: tetramethylsilane...
-
Hiyama coupling is a palladium-catalyzed cross-coupling
reaction of
organosilanes with
organic halides used in
organic chemistry to form carbon–carbon...
- protein, and/or
breakdown of the
protein into
nonfunctional portions.
Organosilanes create a
network of
electrically charged molecules on the surface, which...
- 239. Larson, G. L.; Fry, J. L., "Ionic and organometallic-catalyzed
organosilane reductions",
Organic Reactions 2008, 71, 1-737. doi:10.1002/0471264180...
- also
known as silylbenzene, a
colorless liquid, is one of the
simplest organosilanes with the
formula C6H5SiH3. It is
structurally related to toluene, with...
-
nucleophilic attack of the
conjugate base on the
intermediate carbocation. In
organosilane reductions of
substrates bearing prostereogenic groups, diastereoselectivity...
- kJ/mol, and SiHMe3 398 kJ/mol.
While diverse applications exist for
organosilanes,
silane itself has one
dominant application, as a
precursor to elemental...
-
generation of a carbocation, rate-determining
hydride transfer from the
organosilane occurs to
yield a
reduced product.
Retention of
configuration at silicon...
-
widely known by
various names such as Quat-Silane, SiQuats, Si-Qacs,
Organosilane and Sil-Quats.
Synthesis is
typically conducted in a methanol, however...
-
fluoride ions and alkoxides,
although the
latter often deprotonate the
organosilane to a
silicon ylide instead. As a
covalent hydride source, hydrosilanes...
