-
pyramidal structures.
Organophosphines are
generally colorless,
lipophilic liquids or solids. The
parent of the
organophosphines is
phosphine (PH3). Organophophines...
-
pyramidal structure.
Phosphines are
compounds that
include PH3 and the
organophosphines,
which are
derived from PH3 by
substituting one or more
hydrogen atoms...
-
oxidation state with soft
ligands such as thioethers, thiolates, and
organophosphines. Au(I)
compounds are
typically linear. A good
example is Au(CN)−2,...
- This
colourless viscous liquid is
commonly used in the
synthesis of
organophosphines.
Dichlorophenylphosphine is
commercially available. It may be prepared...
- of
phosphonium salts can be
prepared by
alkylation and
arylation of
organophosphines: PR3 + R'X → [PR3R'+]X− The
methylation of
triphenylphosphine is the...
- P–P bonds.
Examples include catenated derivatives of
phosphine and
organophosphines.
Compounds containing P=P
double bonds have also been observed, although...
- RP(O)(H)OH + 2 RPH2
Phosphine oxide are
typically produced by
oxidation of
organophosphines. The
oxygen in air is
often sufficiently oxidizing to
fully convert...
-
formula R3−nHnPBH3. They are
Lewis acid-Lewis base
adducts derived from
organophosphines (PR3−nHn) and
borane (BH3). They are
generally colorless or
white solids...
- ions. Ni(III) can be
stabilized by σ-donor
ligands such as
thiols and
organophosphines. Ni(III)
occurs in
nickel oxide hydroxide,
which is used as the cathode...
- amines, water, carboxylates,
fluoride and
chloride typical soft bases:
organophosphines, thioethers,
carbon monoxide,
iodide For example, an
amine will displace...
