- In
organometallic chemistry,
organolithium reagents are
chemical compounds that
contain carbon–lithium (C–Li) bonds.
These reagents are
important in organic...
-
August 2014). "Preparation, Properties, and Safe
Handling of
Commercial Organolithiums: Alkyllithiums,
Lithium sec-Organoamides, and
Lithium Alkoxides". Organic...
-
Murahashi Coupling is a
cross coupling reaction. The
coupling partners are
organolithiums and
organic halides.
Transition metal catalysts are required. The reaction...
- (HCl) as byproducts.
Carboxylic acids react with
Grignard reagents and
organolithiums to form ketones. The
first equivalent of
nucleophile acts as a base...
-
Warren and Wothers. He also
wrote Organolithiums:
Selectivity for Synthesis,
which concerns the use of
organolithium compounds in
organic synthetic reactions...
-
equivalent of
organolithium. Alternatively, they may be
formed by the
treatment of a copper(I)
halide with two
equivalents of
organolithium. They undergo...
-
react usefully with
carbon nucleophiles. Instead,
Grignard reagents and
organolithiums deprotonate an
amide N-H bond.
Tertiary amides do not
experience this...
-
reactions that
involve very
strong bases, such as the
preparation of
organolithiums. For example,
butyllithiums are
typically supplied as a
hexane solution...
- is a basic, bulky, and flexible,
tridentate ligand that is a used in
organolithium chemistry. It is a
colorless liquid,
although impure samples appear...
- the carbonyl-carbon. As a result,
while imines can
still react with
organolithiums, they don't
react with
other nucleophiles (including aza enolates) to...
