- In
organometallic chemistry,
organolithium reagents are
chemical compounds that
contain carbon–lithium (C–Li) bonds.
These reagents are
important in organic...
-
organometallic reagent. The most
common classes of
metallated compounds are
organolithium reagents and
Grignard reagents. However,
other organometallic compounds...
- n-Butyllithium C4H9Li (abbreviated n-BuLi) is an
organolithium reagent. It is
widely used as a
polymerization initiator in the
production of elastomers...
- the
preparation of
organolithium compounds. Two
kinds of lithium–halogen
exchange can be considered:
reactions involving organolithium compounds and reactions...
- is a basic, bulky, and flexible,
tridentate ligand that is a used in
organolithium chemistry. It is a
colorless liquid,
although impure samples appear...
-
Murahashi Coupling is a
cross coupling reaction. The
coupling partners are
organolithiums and
organic halides.
Transition metal catalysts are required. The reaction...
- with acid- or base-catalysis.
Carbonation of a
Grignard reagent and
organolithium reagents: RLi + CO2 → RCO−2Li+ RCO−2Li+ + HCl → RCO2H + LiCl Halogenation...
-
contain a
little CeOCl from hydrolysis, but it is
suitable for use with
organolithium and
Grignard reagents. Pure
anhydrous CeCl3 can be made by dehydration...
-
equivalent of
organolithium. Alternatively, they may be
formed by the
treatment of a copper(I)
halide with two
equivalents of
organolithium. They undergo...
- (Grignard-Grisius-Cormas-Gilman)
reaction scheme. In this aspect, they are
similar to
organolithium reagents.
Grignard reagents are
rarely isolated as solids. Instead,...
