- In
organometallic chemistry,
organolithium reagents are
chemical compounds that
contain carbon–lithium (C–Li) bonds.
These reagents are
important in organic...
-
equivalent of
organolithium. Alternatively, they may be
formed by the
treatment of a copper(I)
halide with two
equivalents of
organolithium. They undergo...
- fine chemicals,
organolithium compounds function as
strong bases and as
reagents for the
formation of carbon-carbon bonds.
Organolithium compounds are prepared...
- with acid- or base-catalysis.
Carbonation of a
Grignard reagent and
organolithium reagents: RLi + CO2 → RCO−2Li+ RCO−2Li+ + HCl → RCO2H + LiCl Halogenation...
- the
preparation of
organolithium compounds. Two
kinds of lithium–halogen
exchange can be considered:
reactions involving organolithium compounds and reactions...
-
organometallic reagent. The most
common classes of
metallated compounds are
organolithium reagents and
Grignard reagents. However,
other organometallic compounds...
- most
stable organometallic compounds,
which are
bonded covalently.
Organolithium compounds are
electrically non-conducting
volatile solids or liquids...
-
susceptible to
formylation by
paraformaldehyde to give salicylaldehyde. Like
organolithium compounds,
Grignard reagents are
useful for
forming carbon–heteroatom...
- is a basic, bulky, and flexible,
tridentate ligand that is a used in
organolithium chemistry. It is a
colorless liquid,
although impure samples appear...
-
Murahashi Coupling is a
cross coupling reaction. The
coupling partners are
organolithiums and
organic halides.
Transition metal catalysts are required. The reaction...
