- of
organocopper reagents involve species containing copper-carbon
bonds acting as
nucleophiles in the
presence of
organic electrophiles.
Organocopper reagents...
-
Organocopper chemistry is the
study of the
physical properties, reactions, and
synthesis of
organocopper compounds,
which are
organometallic compounds...
- properties.
Compounds that
contain a carbon-copper bond are
known as
organocopper compounds. They are very
reactive towards oxygen to form copper(I) oxide...
- copper(II) salts.
Compounds that
contain a carbon-copper bond are
known as
organocopper compounds. They are very
reactive towards oxygen to form copper(I) oxide...
- {\displaystyle {\ce {R'-X}}} ) to form a new alkane, as well as an ill-defined
organocopper species and
lithium (pseudo)halide as byproducts. Li+[R–Cu–R]− + R′–X →...
- transfer, only the R
group does.
Cuprate (chemistry) J. F.
Normant (1972). "
Organocopper(I)
Compounds and
Organocuprates in Synthesis". Synthesis. 1972 (2): 63–80...
- "Transmetalation
reactions producing organocopper compounds". In Rappoport, Z.; Marek, I. (eds.). The
Chemistry of
Organocopper Compounds. Vol. 1. John Wiley...
- used
today in
organic synthesis: This
finding led to the
development of
organocopper chemistry. For example, CuCl
reacts with
methyllithium (CH3Li) to form...
-
diphenylcuprate bis(diethyl etherate) is an
example of a
Gilman reagent, a type of
organocopper complex frequently emplo**** in
organic synthesis.
Adenosylcobalamin is...
- +2,
surrounded by four
chloride ions. 2.
Organic cuprates:
These are
organocopper compounds, some of
which having a
general formula of [CuR2]−,
where copper...
