- from triisobutylaluminium: 2 i-Bu3Al → (i-Bu2AlH)2 + 2 (CH3)2C=CH2
Organoaluminum compounds can
react with
alkenes and alkynes,
resulting in the net addition...
- are used in
polymerization reactions in
combination with cocatalysts,
organoaluminum compounds such as triethylaluminium, Al(C2H5)3. This
class of catalyst...
-
organoaluminium compound is a
reagent in
organic synthesis. Like most
organoaluminum compounds, the compound's
structure is most
probably more than that...
-
Negishi and
coworkers originally investigated the cross-coupling of
organoaluminum reagents in 1976
initially employing Ni and Pd as the
transition metal...
-
solid pre-catalyst, the δ-crystalline form of TiCl3, and
solution of an
organoaluminum cocatalyst, such as Al(C2H5)3. The
second type of pre-catalyst is supported...
-
These catalysts are
activated with
special cocatalysts containing an
organoaluminum compound such as Al(C2H5)3 and the
second type of a modifier. The catalysts...
-
August 2017.
Retrieved 6
September 2017. M. Witt; H.W.
Roesky (2000). "
Organoaluminum chemistry at the
forefront of
research and development" (PDF). Curr...
- metal-alkyl complex, e.g. organomercury, organolead, or a
mixed lithium-
organoaluminum compound. The
parent compound of the
phosphines is PH3,
called phosphine...
- M.; Matsumura, Y.; Sakane, S.; Hattori, K.; Yamamoto, H. (1983). "
Organoaluminum-promoted
Beckmann rearrangement of
oxime sulfonates". J. Am. Chem. Soc...
-
alkene +
organoaluminum compound +
chiral zirconium catalyst +
oxygen (optional) ↓
chiral alcohol +
aluminum oxide...
