- can act as
nucleophiles.
Because nucleophiles donate electrons, they are
Lewis bases.
Nucleophilic describes the
affinity of a
nucleophile to bond with...
-
mechanism that is
common in
organic chemistry. In the SN2 reaction, a
strong nucleophile forms a new bond to an sp3-hybridised
carbon atom via a
backside attack...
-
chemical reactions in
which an electron-rich
chemical species (known as a
nucleophile)
replaces a
functional group within another electron-deficient molecule...
- amidases, esterases, acylases,
lipases and β-lactamases). An acid-base-
nucleophile triad is a
common motif for
generating a
nucleophilic residue for covalent...
- and zero-order
dependence on the
nucleophile. This
relationship holds for
situations where the
amount of
nucleophile is much
greater than that of the...
-
addition is a
reaction between a
Michael donor (an
enolate or
other nucleophile) and a
Michael acceptor (usually an α,β-unsaturated carbonyl) to produce...
- From the
biological perspective, the key
reactions involve addition of
nucleophiles to the
formyl carbon in the
formation of
imines (oxidative deamination)...
-
supports the
stereochemical ****ignment). An
Ambident nucleophile refers to an
anionic nucleophile that
exhibits resonance delocalization of its negative...
- pair from the
nucleophile attacks the
substrate forming a new bond,
while the
leaving group departs with an
electron pair. The
nucleophile may be electrically...
-
usually minor constituent of water. It
functions as a base, a ligand, a
nucleophile, and a catalyst. The
hydroxide ion
forms salts, some of
which dissociate...
