-
steer homogeneous catalysis.
Porphyrin ligands can be
innocent (−2) or
noninnocent (−1). In the
enzymes chloroperoxidase and
cytochrome P450, the porphyrin...
- pi-acceptor properties. Several,
especially the
diiminopyridines are
noninnocent ligands. Many
Schiff base
ligands are
derived from
alkyl diamines and...
- ligand,
metallocorroles are
formally high-valent.
Several are redox-
noninnocent, with a
corrole radical-dianion ligand. A
second difference between corroles...
-
triplet ground state for this complex, the bis(pyridine)
adduct features noninnocent acac2-
ligand attached to Cr(III). Chromium(II)
acetylacetonate is prepared...
- of
models for iron and
manganese metalloenzymes,
metal complexes of
noninnocent ligands, and
magnetic interactions in
polynuclear metal complexes. Wieghardt...
-
attention as dyes. They are of
academic interest because the
dithiolenes are
noninnocent ligands. The
lengths of the C-S and C-C
bonds in the backbone, respectively...
- above, the bis(pyridine)
adduct of chromium(II)
acetylacetonate features noninnocent acac2- ligand.
Treatment of TiCl4 with
acetylacetone gives TiCl2(acac)2...
-
donors out of planarity. No
evidence indicates that
salen is a redox-
noninnocent ligand. The
pyridine adduct of the cobalt(II)
complex Co(salen)(py) (salcomine)...
-
results for
other properties such as bond
distances and spin densities.
Noninnocent ligands. He has had an
abiding interest in the
phenomenon of
ligand noninnocence...
- [M(py)6]z
complexes are rare and
apparently labile.
Bipyridine is a redox-
noninnocent ligand, as
illustrated by the
existence of
complexes such as [Cr(bipy)3]0...
