- pi-acceptor properties. Several,
especially the
diiminopyridines are
noninnocent ligands. Many
Schiff base
ligands are
derived from
alkyl diamines and...
-
steer homogeneous catalysis.
Porphyrin ligands can be
innocent (2-) or
noninnocent (1-). In the
enzymes chloroperoxidase and
cytochrome P450, the porphyrin...
-
attention as dyes. They are of
academic interest because the
dithiolenes are
noninnocent ligands. The
lengths of the C-S and C-C
bonds in the backbone, respectively...
-
donors out of planarity. No
evidence indicates that
salen is a redox-
noninnocent ligand. The
pyridine adduct of the cobalt(II)
complex Co(salen)(py) (salcomine)...
- above, the bis(pyridine)
adduct of chromium(II)
acetylacetonate features noninnocent acac2- ligand.
Treatment of TiCl4 with
acetylacetone gives TiCl2(acac)2...
- of
models for iron and
manganese metalloenzymes,
metal complexes of
noninnocent ligands, and
magnetic interactions in
polynuclear metal complexes. Wieghardt...
- ligand,
metallocorroles are
formally high-valent.
Several are redox-
noninnocent, with a
corrole radical-dianion ligand. A
second difference between corroles...
- Zn) and
Their Monocationic Analogues:
Mixed Valency Involving a
Redox Noninnocent Ligand System".
Journal of the
American Chemical Society. 130 (10): 3181–3197...
- "Stabilizing
Monoatomic Two-Coordinate Bi****h(I) and Bi****h(II)
Using a
Redox Noninnocent Bis(germylene) Ligand".
Journal of the
American Chemical Society. 146...
-
unambiguity of the result. However, for some
complicated species possessing noninnocent ligands, the
results become ambiguous. For example,
several copper-trifluoromethyl...
