- case of
cyclic nitroxides, five-membered ring
systems have been
shown to
cleave more
slowly than six-membered
rings and
acyclic nitroxides with t-butyl...
- metabolism, and
inhibits Fenton chemistry. 4-Hydroxy-TEMPO,
along with
related nitroxides, are
being studied for
their potential antioxidant properties. On an industrial-scale...
-
general structure R2N–O•. It is
commonly known as a
nitroxyl radical or a
nitroxide,
however IUPAC discourages the use of
these terms, as they erroneously...
- a short-lived
intermediate in solution. Its
conjugate base, NO−, the
nitroxide anion, is the
reduced form of
nitric oxide (NO) and is
isoelectronic with...
-
September 2018. Damiani, E.; Greci, L.; Parsons, R.; Knowland, J. (1999). "
Nitroxide radicals protect DNA from
damage when
illuminated in
vitro in the presence...
- N-oxoammonium species.
Nitroxides may also be used in
catalytic amounts in the
presence of a
stoichiometric amount of a
terminal oxidant.
Nitroxide radical species...
-
prevent radiation-induced dermatitis.
TEMPOL and
similar SOD-mimetic
nitroxides exhibit a
multiplicity of
actions in
diseases involving oxidative stress...
-
Synthesis Chain polymerization Radical polymerization RDRP] ATRP RAFT
Nitroxide-mediated
radical polymerization Step
polymerization Condensation polymerization...
-
which are
stabilized by
steric and/or
resonance effects. For example, the
nitroxide radical in (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO), the most common...
- used as a
nitroxide spin label. MTSL is bifunctional,
consisting of the
nitroxide and the
thiosulfonate ester functional groups. The
nitroxide label is...
